Ashlee Simpson is taking her breakup with Pete Wentz in stride. The younger Simpson sister went to Les Deux in L.A. Saturday night and picked up Chad Hugo from the Neptunes, spies said. “She tried to pick up Ryan Phillippe, but he wasn’t interested. So then she hung out with Chad all night and left with him.” Simpson’s rep fumed, “That is not true. She is working with Chad on her new album. There is nothing romantic going on.”