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Angelina Jolie, goodwill ambassador for the U.N. High Commissioner for Refugees, waves while visiting Syrian refugees at the Altinozu refugee camp near the Syrian border. AP Photo/Vadim Ghirda
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Angelina Jolie greets refugees as she exits her van. AP Photo
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Passionate Goodwill Ambassador Jolie gestures to the people as she leaves from a Syrian refugee camp in the southern Turkish town of Altinozu in Hatay province. REUTERS
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Angelina Jolie models in her most natural state for the Louis Vuitton’s ‘Core Values’ campain in Cambodia. Annie Leibovitz/Louis Vuitton
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Angelina Jolie take the kids to a indoor playpark in Malta looking quite fashionable. Splash News
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Angelina Jolie attends “The Tree Of Life” Los Angeles Premiere with Brad Pitt who stars in this 2011 film. WireImage
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Brangie attends the Los Angeles premiere of “Kung Fu Panda 2” at Grauman’s Chinese Theatre. 2011 film Kung Fu Panda 2, stars Angelina as the voice of Tigress. WireImage
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Actors James Hong, the voice of Mr. Ping and Angelina Jolie, the voice of Tigress arrive at the Los Angeles premiere Of DreamWorks Animation’s “Kung Fu Panda 2” held at Grauman’s Chinese Theatre. Getty Images
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Angelina speaks to a young fan at the premiere of “Kung Fu Panda 2” in Los Angeles. AP Photo
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Look at Po’s mischievous smile! Actor Angelina Jolie sends one right back as she arrives on the red carpet for the LA premiere of “Kung Fu Panda 2.” AFP/Getty Images
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Co-stars, Angelina Jolie, Jack Black, and Seth Rogen pose for a pic at their “Kung Fu Panda 2” premiere. Getty Images
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Angelina Jolie, during a visit to Ramstein Air Base in Germany, meets with wounded warriors in an effort to boost their morale as they prepare to travel back to the U.S. for the first time since their injuries. RAMEY PHOTO
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Brad and Angelina strike a regal pose at the premiere of “The Tree of Life,” coinciding with the 64th Annual Cannes Film Festival at the Palaise des Festival. INFevents.com
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Angeline Jolie models solo at the “The Tree of Life” Premiere in Cannes, France. Barcroft Media
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Jack Black coaxes a sexy wide grin from Angelina Jolie from who we usually get a sultry stare. AP Photo
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Angelina Jolie talks with Tunisian Foreign Minister Mouldi Kefi during her travels to the Tunisian-Libyan border to urge greater international support for people fleeing Libya. AP Photo
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A pensive Angelina walks with UNHCR Protection Officer Patrick Mansour, second from right, at the Ras Djir Tunis-Libyan border. AP Photo
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Angelina Jolie trendily took off from LAX to the Middle East for a UN mission. Splash News
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Mommy Angelina holds the hands of her two youngest children, Vivienne and Knox in Los Angeles. Splash News
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Angelina Jolie arrives for the Golden Globe Awards in Beverly Hills, California looking striking in her green gown. AP Photo
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Actress Angelina Jolie attends the ‘The Tourist’ premiere in Roma. WireImage
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Angelina Jolie goes shopping at “Lee’s Art Shop” with her children, Maddox, Pax, Zahara and Shiloh in New York City. INFphoto.com
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Power couple Brad Pitt and Angelina Jolie acknowledge adoring fans as they attend the ‘Megamind’ French premiere in Paris. AP Photo
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Angelina Jolie directs her new film in Estergom, Hungary. She looks freezing! INFphoto.com
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Angelina Jolie speaks to one of the actors on the set of her new film in Budapest, Hungary. The film is about a love story during the Bosnian-Serbian war and is Jolie’s first foray into directing. INFphoto.com
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Supportive Brad Pitt joins Angelina Jolie on the set of her new film in Budapest, Hungary. INFphoto.com
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Jolie has been visiting Pakistan’s northwest region to draw the world’s attention towards the plight of 21 million people affected by the country’s worst-ever floods. She visits displaced victims at Kandaro II Camp in Nowshera, Khyber Pakhtunkhwa in Pakistan. UNHCR
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Angelina visits a camp set up for people displaced by heavy floods, in Mohib Banda near Peshawar, Pakistan. AP Photo
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Who? Me? Angelina Jolie arrives at the Paris Premiere of ‘Salt’ at Le Grand Lex. She told reporters that she brought only her two-year-old twins, Vivienne and Knox with her for the trip. INFphoto.com
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Teasing Angelina Jolie arrives at the premiere of Sony Pictures’ ‘Salt’ at Grauman’s Chinese Theatre in Hollywood, California. Getty Images
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Angelina poses for photographers in Cancun, Mexico during a media event to promote her new movie Salt in which she plays the role of Evelyn Salt, a CIA officer accused of being a Russian spy. AP Photo
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“Alexander” press conference with Angelina Jolie. Wireimage.com
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Angelina in 1999. David Rentas/New York Post
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Billy Bob Thornton and Angelina Jolie in a scene from “Pushing Tin.”‘ Copy Color Slide
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Angelina Jolie at the Regency Hotel. Michael Sofronski/The New York Post
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Angelina Jolie arrives for the 73rd annual Academy Awards ceremony in 2001. AP
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Billy Bob Thornton and Angelina Jolie arrive at the premiere of “Bandits” in Octorber, 2001. AP
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Angelina Jolie arrives for the 58th Annual Golden Globe Awards in Beverly Hills, Calif., Sunday, Jan. 21, 2001. AP
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A still shot from “Laura Croft Tomb Raider,” the film which many credit for making Angelina Jolie a household name. Paramount Pictures
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Angelnia Jolie attends the UN’s meeting of Goodwill Ambassadors and Messengers of Peace in 2002. UDV-LONDON FEATURES
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Actress Angelina Jolie has a new tattoo applied to her back in Pathum Thani, Thailand, Wednesday, April 23, 2003. AP
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Angelina Jolie stops by MTV’s TRL studios in July 2003 to promoite a new film. Wireimage.com
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Jolie on the red carpet in Munich during the premiere of “Lara Croft Tomb Raider: The Cradle of Life” in 2003. REUTERS
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Jolie arrives at the BAFTA awards in London in 2003. REUTERS
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Angelina Jolie arrives for the 76th annual Academy Awards in 2004 in Los Angeles. AP
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Angelina Jolie attends the ”Peace One Day” screening in New York City, just days after Brad Pitt and Jennifer Aniston finalized their divorce in Sept. 2005. Wireimage.com
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Jolie stands with U.S. Secretary of State Condoleezza Rice and Senator Hillary Clinton (D-NY) attend the Global Business Coalition gala awards dinner in Washington, D.C., in Septemter 2008. REUTERS
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Jolie arrives at the United Nations Association of the USA 2005 annual dinner, where she was presented with the Global Humanitarian Action Award, in New York, in October 2005. AP
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Angelina Jolie and Brad Pitt promote “Mr. and Mrs. Smith” in March 2005. The couple kept noticeably far apart during the photo op as rumors swirled that they were an item, despite Pitt’s marriage to Aniston. Wireimage.com
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Angelina Jolie carries her son Maddox while on a break from promoting “Mr and Mrs. Smith” in New York city in 2005. INFPhoto.com
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Angie at the “Oceans Thirteen” premiere at Cannes Film Festival. Nick Sadler/startraksphoto.com
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Here is Angelina Jolie as you have never seen her before as an awkward teenager already showing the distinctive features that made her a superstar. Splashnews.com